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PBT EE-4401F件 →,PA6 1015GH35 PP MPS20M 、→,POP 4000 、‖。PC I2600 、→,EPDM 27 、→,PC/ABS CM8622 、→,PTFE D/W601 PP HP560P 、→,PP HA686J 、‖。PC/ABS C1110HF-100 、‖。POM FK66003 PA6 BG-50S BK LDPE 1800H PC DF002ERJ 、→,EBA FT3030 、‖。PBT 420-1001 、‖。PA66 1603 EVA LD706.15Molding 、→,PPS C1305 、‖。ABS VD100 、‖。TPEE BT-1063D PC FL920 、→,PP J1400 EPDM 4021 、‖。PBT C 1202 、‖。PA66 ST701HS 、‖。PC 953A-116 PC HM-3301GL 、→,PC/ABS LAY1004SG 、→,PA6 K225-KS LCP E7006L 、‖。PA66 RX03013 PC/ABS C2800-BK TPU 80AHTDP TPE M12050 、‖。PC ETIR320 PA66 73G25HSL 、‖。PC/ABS S5210 HDPE MD700 PA6 BU50I 、→,PMMA SRB100 、→,ASA AVR300 、→,TPU 1185AFHF 、‖。PC/ABS PC、→,DAP K43V 、‖。PP 9800 ABS SG-725 、‖。PBT S7926 TPE FN005 、‖。PC/ABS FR3005 、‖。PBT RF300G4 PP MFB22S LDPE HP2022J PBT 420 、→,EVA H2041 、→,PC/PET DA003 、→,PC D20001 PA66/PTFE RL-4540 、‖。TPE G7970-9001-02 、‖。PA66 RE0029 PP 1692 PP RJ370MO HDPE 3300F TPU TE80AP LCP NT 1500/300 、‖。 2103 、→,PA46 TW271F8 、‖。PP J501 TPE 5062 、‖。PC S2000UR PC 121R-111 、→,PC/ABS HM-1202GS 、‖。PP HF006SA 、→,AS GR-5030F 、→,PMMA LH752 ABS ZFJ5 、→,SEPS 1522-55S 、‖。TPU 49-46/23 、→,EVA LD720 、→,PC/ABS VB-1108RS 、‖。PP B2 HDPE BS4641 、‖。POM MT12U01 、‖。PC DL003 、‖。PC DCL329XZ PC URC2500 、→,EVA PX1007 、→,PA612 2612 、→,LLDPE PF1320AA 、→,TPV W651B HDPE 5310M HDPE AL55-003 PBT 3314 、‖。PC G-3410 NC PA66 90G55 BK PA6 TN 5000 、→,PA12 LX9102 PMMA V020 、‖。TPE TO-1175A PEI PDX-E-99545 BK 、‖。PPO 300H BK PC DX04489C PA11 BESNO-TL PBT B7375 PP 4320WZ 、→,DAP 5562 、→,EVA 470A 、‖。PC ML-4104ZHP ABS NP2MT 、→,PA6 PFN16 、→,LDPE NA208 PP PY-200GP PP FC9413G HDPE 5100ST ABS EX23X PA6 6MV14 PBT 2302G1/20 、‖。TPU U-80A10 PA9T G2330 12 PC/ABS 2253 、
LDPE The film can be used in packaging materials and capacitor films.
For the food packaging industry, the gas permeability of the biaxially stretched PP film is lower. To reduce permeability, the first is to reduce the permeability of PP material, which can be achieved by filling and modifying, but the effect is not very obvious. The two is to reduce permeability through blocking the contact between PP film and gas. It is also easy to achieve the following 2 methods.
BOPP can be used to separate gas by spraying, such as spraying two vinyl chloride or vinylidene ethyl alcohol to the surface of the membrane, with a thickness of about 0.0075 millimeters.
Another method is vacuum aluminizing, with a thickness of about 0.0002 millimeters to block oxygen and so on.
3.PP needling omentum
The membrane is an upgrading product of the tear film, and it can be used in sewing thread, carpet weaving, marine fishing and other industries.
The process flow is as follows:
Feeding, extrusion, film cooling, cutting and dividing wire, three roll traction, heating, stretching, needle forming fiber, heat treatment, cooling setting and winding.
The temperature of the fuselage: 220, 230, 260, 255 C, the head temperature 250 C, the die head 250 centigrade, the PP melt index 1.5-4 g /10. The film cooling, water temperature 38 C, hot stretching temperature 150-165 degrees C, tensile multiple 5-6 times, cooling roll speed is lower than heat treatment roll speed 2-5%, stretching speed of 240 meters / points.
4.PP isolation membrane
The PP isolation membrane can be used as an isolating layer between the conductor and the rubber insulation in the wire and cable. It can prevent adhesion between metal conductor and rubber sleeve.
The process flow is as follows:
Ingredients, kneading, extrusion, blowing and cooling, traction, cutting, winding, cutting and inspection.
The melting index of the PP material is below 3.5 g /10. The extruder temperature is 180, 190-200, 200-210 C, and the temperature of the die head
EEA In storage, we should keep away from the fire source, heat insulation, keep dry and clean in the warehouse, strictly prohibit any impurities mixed, strictly prohibit the sun and rain. Transportation should be stored in a clean, dry and roofed carriage or cabin, and no sharp objects such as iron nails are allowed. It is strictly prohibited to mix organic solvents such as flammable aromatic hydrocarbons and halogenated hydrocarbons. For example, the four liters of mineral water in a farmer's spring is a big bucket, which is the material.
Recycling
(2) the typical representative of the ring tube reactor process ring tube reactor process is the Phillips process of Phillips company and the Innovene S process of INEOS company. Phillips process using isobutane as diluent, the chromium catalyst, the catalyst must be activated before use, isobutane activated catalyst powder with high purity under the protection of nitrogen formed catalyst slurry, and then enter the loop reactor, ethylene monomer after refining, and hydrogen, a TIGI olefin monomer 1 pre mixed and then injected into the loop reactor, the ethylene production of polyethylene in the presence of catalyst. The axial flow pump maintains the high speed flow and very uniform mixing of the material in the reactor, and the reaction heat is evacuated evenly from the jacket cooling water. The MI range of this process is 0.15 - 100, and the density is 0.936 - 0.972 g/cm3. The characteristics of the reactor loop is: less equipment, short process, low investment cost; do not produce wax and oligomer, not sticking to the wall; the powder of good shape, easy to transport; depending on the reaction heat jacket of the reactor cooling water out, heat removing easy, convenient adjustment; raw material demand is higher, need purification; copolymerization the monomer using hexene; using isobutane as solvent, the easy escape of residual solvents. The process flow is as follows: fresh polymerized ethylene is mixed with molecular weight regulator hydrogen, antifreeze and circulating diluent isobutane after drying, and then sent into a multi loop continuous flow reactor, and catalyst is added into isobutane into a reactor. The reaction temperature is 106.7 degrees centigrade, and the pressure is 3.9MPa. The polymer and the diluent residual pulp through the axial flow pump at the speed of 6m/s through the loop reactor. Reactor water cooling control reaction temperature set in the solid polymer by loop reactor outlet vertical settlement. As a result, the concentration of slurry can reach 55% and the conversion rate is 98% - 99%. The polymer is discharged after the flash evaporation to discharge the isobutane and the residual monomer into the diluent recovery unit. Other solid polymers are mixed with additives and granulation. 2, gas phase polymerization and gas phase polymerization (gas phase fluidized bed method) typical process for Innovene technology univation Technology chemical company DOW univation technology and INNOS company by low pressure gas phase fluidized bed reactor using z/n catalyst and catalyst, purification of raw material into the reactor, resulting in polymerization catalyst storage under the action of reaction in 85~110. [. Pressure was conducted for 2.41 MPa, the single pass conversion of ethylene is about 1% ~ 2%, the reaction heat removal mainly through the cooling cycle logistics, MI range of products for the production of 0.01 to 150, the density ranges from 0.915 to 0.970 g/cm3. The characteristics of gas phase fluidized bed polymerization process is: low operating pressure, low temperature; can produce full density polyethylene; catalyst system including titanium, chromium; metallocene catalyst; high purity of raw material, all raw materials are to be refined; without solvent, low energy consumption, low operation cost and maintenance. The production process is: dry monomers with hydrogen added to a reactor system, the raw material into a large circulation steam flow circuit, and through the gas distribution by entering the large fluidized bed reactor at the bottom, according to the design of the reactor material 69.57% (ethylene vinyl content of 99.9%, 0.1%, 10.43%, 7.56% hydrogen oxide) ethane and 12.44% nitrogen. This raw gas consists of the production of the product with the 8g/10min melt index and the density of the 0.964g/cm3. The catalyst consists of titanium trichloride and tetrahydrofuran for two Magnesium Oxide mixture accelerator, AlEt3 catalyst. The catalyst enters the device in the form of solid state and nitrogen from the non pain reactor. The operating temperature is 105 centigrade, and the specific temperature is determined according to the brand name. The reactor pressure is 2.0MPa, and the reaction gas comes out from the top of the reaction. The cyclone separates the catalyst containing solid material and sends it back to the reactor. Then the gas from the cyclone separator is circulated to the bottom of the reactor after the compression and circulating coolers. The reactor discharge through an air lock system intermittently to product tank. Part of the gas entering the discharge tank enters the compressor cycle system through the upper buffer tank, filter, gas cooler, and separation tank. The polymer comes out from the lower part of the discharge tank and enters the washing tank and the post treatment system.